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    Please use this identifier to cite or link to this item: https://ir.fy.edu.tw:8080/ir/handle/987654321/1336


    Title: Structures and Magnetic Properties of Two Copper (Ⅱ) Complexes with 2, 5-Dichloro-3, 6-dihydroxy-1, 4-benzoquinone Dianionic and Tetrachloroquinone Ligand
    Authors: Yun-Ho Chung;Szu-I Fang;Shu-Hui Fang;Hsin-Huang Lin;Shyh-Yeon Liou
    Contributors: 輔英科技大學 共同教育中心 語言教育中心
    Keywords: 2,2'-Dipyridylamine,Laccase reaction,Tetrachlorocatechol,Chloranilic acid,2,5-Dichloro-3,6-dihydroxy-1,4-benzoquinone dianionic,Bleaney-Bowers equation
    Date: 2009-12-01
    Issue Date: 2010-09-24 14:42:26 (UTC+8)
    Abstract: The polynuclear copper (Ⅱ) complex [Cu2 (Hdpa)2 (µ-ClDHBQ) (ClO4)2](subscript n), 1 is bridged by C1DHBQ^(-2) (2, 5-dichloro-3, 6-dihydroxy-1, 4-benzoquinone dianionic) and 2, 2'-dipyridylamine (Hdpa). In the axial position, Cu is connected with the oxygen atom of ClO4^(superscript -) The perchlorate anion may be envisaged as a monodentate O-bound ligand. Through the bond bridge of O-Cu…O-C1, the binuclear compound [Cu2 (Hdpa)2 (µ-C1DHBQ) (ClO4)2] is strung together into a long chain compound. Tetrachlorocatechol underwent partial oxidation/hydrolysis/dechlorination processes to produce C1DHBQ2. The other mononuclear complex [Cu (Hdpa) (TeCQ)] (DMF), 2, in which tetrachloroquinone (TeCQ) was produced by oxidation of tetrachlorocatechol (TeCC), therefore complex 2 is in the quinone form. The magnetic susceptibility measurements show antiferromagnetic coupling with J=-11.9cm^(-1), θ=2.6K, and g=2.05 for complex 1. Complex 2 exhibits the typical paramagnetic behavior of s=1/2.
    Relation: Journal of the Chinese Chemical Society56(6),P1099-1107
    Appears in Collections:[語言教育中心] 期刊論文

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